1-Octene → Octane

HRID 1885050Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1885050
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH2:9]([O:13]CCCC)CCC>C1COCC1>[CH3:1][CH:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[CH:9]=[O:13].[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Komponenten

6

Edukt 2

HCID 81251-OcteneHCID 8909Butyl ether

Produkt 3

HCID 356OctaneHCID 81251-OcteneHCID 245832-Methyloctanal

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

A mixture of Rh(CO)2(acac)(3 mg,0.012 mmole), branched polymer3 (insoluble) (26 mg), 1-Octene (98 mg,0.9 mmole), and THF(0.5 ml) was heated at 80 C. under 100 psi of CO/H2(1/1) for 1 hr. Butyl ether(2.6 mg, 0.02 mmole) was added into the mixture as the internal standard and the mixture was analyzed by Gas Chromatograph with Chrompack CP-SIL 8 column(30 m×0.32 mm ID). 98.8% Conversion was obtained with 40.8 wt % of Nonyl aldehyde, 1.3 wt % of 2-Methyl-1-octanal, 6.2 wt % of Octane, and 29.0 wt % of Octene isomers.

Aufarbeitung

  1. temperaturewas heated at 80 C

Quellen und Nachweise

ORD-Eintrag
ord-5f2b94fde3f948f38b4953a5f07219f0
Quelldatensatz
uspto-grants-2004_07
Patentnummer
US06768028B2

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