Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Cycloheptane | HCID 9265 | — |
| Reactant | Cycloheptanone | HCID 10400 | — |
| Reactant | Tert-Butyl nitrite | HCID 10906 | — |
| Reactant | Cycloheptanone Oxime | HCID 137457 | — |
| Reactant | Nitrocycloheptane | HCID 4189425 | — |
| Reactant | 5-Chloro-2-hydroxy-1H-isoindole-1,3(2H)-dione | HCID 22178410 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | Cycloheptyl Acetate | HCID 11423718 | — |
Reaction Steps
Cycloheptane (1 ml), t-butyl nitrite (1 mmol), 4-chloro-N-hydroxyphthalimide (0.2 mmol), and acetic acid (1 ml) were placed in a flask and were stirred at 80° C. in an atmosphere of argon gas (1 atm=0.101 MPa) for 20 hours. The resulting reaction mixture was analyzed to find that cycloheptanone oxime, nitrocycloheptane, cycloheptanone, and cycloheptyl acetate were formed in yields of 16%, 4%, 6%, and less than 1%, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06768023B2 |
|---|
| Source dataset | uspto-grants-2004_07 |
|---|
| ORD ID | ord-0dc4d9e6cd524ed29fa905cde8c09270 |
|---|
| Source note | uspto-grants-2004_07 |
|---|
