Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Cyclododecane | HCID 9268 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Reactant | Tert-Butyl nitrite | HCID 10906 | — |
| Reactant | Cyclododecanone, oxime | HCID 136762 | — |
| Reactant | Nitrocyclododecane | HCID 292842 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | Cyclododecanone | HCID 13246 | — |
Reaction Steps
Cyclododecane (1 ml), t-butyl nitrite (1 mmol), N-hydroxyphthalimide (0.2 mmol), and acetic acid (1 ml) were placed in a flask and were stirred at 80° C. in an atmosphere of argon gas (1 atm=0.101 MPa) for 20 hours. The resulting reaction mixture was analyzed to find that cyclododecanone oxime, nitrocyclododecane, and cyclododecanone were formed in yields of 41%, 4%, and 9%, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06768023B2 |
|---|
| Source dataset | uspto-grants-2004_07 |
|---|
| ORD ID | ord-523bc0e3724349b08606fa49ad3681bb |
|---|
| Source note | uspto-grants-2004_07 |
|---|
