関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Acetophenone | HCID 7410 | — |
| 反応物 | Ethylbenzene | HCID 7500 | — |
| 反応物 | N-Hydroxyphthalimide | HCID 10665 | — |
| 反応物 | Tert-Butyl nitrite | HCID 10906 | — |
| 反応物 | 1-Nitroethylbenzene | HCID 23618 | — |
| 反応物 | Acetophenonoxime | HCID 69185 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | 1-Phenylethyl Acetate | HCID 62341 | — |
反応手順
Ethylbenzene (1 ml), t-butyl nitrite (1 mmol), N-hydroxyphthalimide (0.2 mmol), and acetic acid (1 ml) were placed in a flask and were stirred at 100° C. in an atmosphere of argon gas (1 atm=0.101 MPa) for 20 hours. The resulting reaction mixture was analyzed to find that acetophenone oxime, (1-nitroethyl)benzene, acetophenone, and α-methylbenzyl acetate were formed in yields of 32%, 5%, 23%, and 15%, respectively.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06768023B2 |
|---|
| 出典データセット | uspto-grants-2004_07 |
|---|
| ORD ID | ord-cd16011e93fa4954bffa561b237bb692 |
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| 出典メモ | uspto-grants-2004_07 |
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