関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Mesitylene | HCID 7947 | — |
| 反応物 | N-Hydroxyphthalimide | HCID 10665 | — |
| 反応物 | Tert-Butyl nitrite | HCID 10906 | — |
| 反応物 | Benzaldehyde, 3,5-dimethyl- | HCID 34225 | — |
| 反応物 | 3,5-Dimethylbenzonitrile | HCID 89718 | — |
| 反応物 | N-[(3,5-Dimethylphenyl)methylidene]hydroxylamine | HCID 71401900 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | Benzenemethanol, 3,5-dimethyl-, 1-acetate | HCID 12229212 | — |
反応手順
Mesitylene (1 ml), t-butyl nitrite (1 mmol), N-hydroxyphthalimide (0.2 mmol), and acetic acid (1 ml) were placed in a flask and were stirred at 60° C. in an atmosphere of argon gas (1 atm=0.101 MPa) for 20 hours. The resulting reaction mixture was analyzed to find that 3,5-dimethylbenzaldehyde oxime, 3,5-dimethylbenzaldehyde, 3,5-dimethylbenzonitrile, and 3,5-dimethylphenylmethyl acetate were formed in yields of 61%, 3%, 4%, and less than 1%, respectively.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06768023B2 |
|---|
| 出典データセット | uspto-grants-2004_07 |
|---|
| ORD ID | ord-6dbe78615a4b4b198597b09087a4073c |
|---|
| 出典メモ | uspto-grants-2004_07 |
|---|
