Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Cyclododecane | HCID 9268 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Reactant | Tert-Butyl nitrite | HCID 10906 | — |
| Reactant | Cyclododecanone, oxime | HCID 136762 | — |
| Reactant | Nitrocyclododecane | HCID 292842 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | Cyclododecanone | HCID 13246 | — |
Reaction Steps
Cyclododecane (1.66 g; 9.88 mmol), t-butylnitrite (2 mmol), N-hydroxyphthalimide (0.4 mmol), and acetic acid (2 ml) were placed in a flask and were stirred at 80° C. in an atmosphere of argon gas for 1 hour. The resulting mixture was further stirred at 180° C. for 5 minutes and was then analyzed to find that cyclododecanone oxime, nitrocyclododecane, and cyclododecanone were formed in yields of 28%, 10%, and 3%, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06768023B2 |
|---|
| Source dataset | uspto-grants-2004_07 |
|---|
| ORD ID | ord-8aa2d793ab554152ae4b592fe9e00489 |
|---|
| Source note | uspto-grants-2004_07 |
|---|
