HCID 15114139, compound → HCID 15114140, compound

HRID 1885100Notes

Reaction equation

HRID 1885100 reaction equation
[CH2:1]([O:11][C:12]1[CH:13]=[C:14]2[C:19](=[CH:20][CH:21]=1)[CH:18]=[C:17]([CH2:22][OH:23])[CH:16]=[CH:15]2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]>C(Cl)(Cl)Cl.[O-2].[O-2].[Mn+4]>[CH2:1]([O:11][C:12]1[CH:13]=[C:14]2[C:19](=[CH:20][CH:21]=1)[CH:18]=[C:17]([CH:22]=[O:23])[CH:16]=[CH:15]2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

4

Reactant 1

HCID 15114139HCID 15114139, compound

Product 1

HCID 15114140HCID 15114140, compound

Reagents, catalysts & solvents 2

HCID 178418406HCID 178418406, compoundCatalystHCID 6212ChloroformSolvent

Procedure

In 10 ml of chloroform, 84 mg (0.43 mmol) of the thus obtained 6-decyloxy-2-hydroxymethylnaphthalene was dissolved, and 235 mg (2.57 mmol) of activated manganese dioxide powder was added. The oxidation reaction was carried out with vigorous stirring at room temperature for 12 hours.

Workup

  1. customThe oxidation reaction

Sources & evidence

ORD record
ord-331fa00e8b004edf98ea4ef3a4378078
Source dataset
uspto-grants-1992_09
Patent number
US05143644

Reaction notes

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