HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyl Sulfoxide → Hydrogen Peroxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyl Sulfoxide | HCID 679 | — |
| Reactant | Hydroxide | HCID 961 | — |
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Aniline | HCID 6115 | — |
| Solvent | Water | HCID 962 | — |
| Product | Hydrogen Peroxide | HCID 784 | — |
| Product | Azobenzene | HCID 2272 | — |
Reaction Steps
The excess hydroxide ions (OH-), dissolved dioxygen (O2), and aniline (PhNH2) reacted in the dimethyl sulfoxide solution to form superoxide ions (O2-.), azobenzene (PhN=NPh), hydrogen peroxide (HOOH), and water (H2O). The dioxygen was introduced by bubbling gaseous dioxygen through the solution of other reactants for 20 minutes, and then purging with argon. The reaction yielded concentrations of 1.4 mM of superoxide ions and 2.5 mM of azobenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05143710 |
| Source dataset | uspto-grants-1992_09 |
| ORD ID | ord-b9f04c128e7a4fb692051d725820fc5f |
| Source note | uspto-grants-1992_09 |