Methyl vinyl ketone → HCID 19878869, compound

HRID 1885508Notes

Reaction equation

HRID 1885508 reaction equation
CC(=O)C=C.CC1C(SC(C)CC(=O)C)CCO1.[CH3:19][C:20]1[S:21][CH:22]=[CH:23][C:24]=1[S:25][CH:26](C)[CH2:27][C:28](=[O:30])[CH3:29]>>[CH3:19][C:20]1[S:21][CH:22]=[CH:23][C:24]=1[S:25][CH2:26][CH2:27][C:28](=[O:30])[CH3:29]

Participants

4

Reactant 3

HCID 6570Methyl vinyl ketoneHCID 19878871HCID 19878871, compoundHCID 19878872HCID 19878872, compound

Product 1

HCID 19878869HCID 19878869, compound

Procedure

When using 2-methyltetrahydrofuryl-3-thiol or 2-methyl-thienyl-3-thiol instead of 2-methylfuryl-3-thiol and 3-buten-2-one instead of 3-penten-2-one, 4-(2-methyl-3-tetrahydrofuryl-thio)-pentan-2-one, 4-(2-methyl-3-thienyl-thio)-pentan-2-one and 4-(2-methyl-3-thienyl-thio)-butan-2-one were obtained.

Sources & evidence

ORD record
ord-f792903d1672438ea37ab79d6f30ecc8
Source dataset
uspto-grants-1992_09
Patent number
US05145703

Reaction notes

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