HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → {[2-(Methoxycarbonyl)phenyl]methyl}(triphenyl)phosphanium bromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | Methyl o-toluate | HCID 33094 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Solvent | Toluene | HCID 1140 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | {[2-(Methoxycarbonyl)phenyl]methyl}(triphenyl)phosphanium bromide | HCID 10743695 | — |
Reaction Steps
Methyl 2-methylbenzoate was treated successively with N-bromosuccinimide in chloroform and triphenylphosphine in toluene to give (o-methoxycarbonylbenzyl)triphenylphosphonium bromide as a white solid, mp. 230°-234° C., 1H NMR (D6 -DMSO) delta 3.36 (3H,s); 5.47 (2H, br d J 17 Hz) ppm.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05145954 |
| Source dataset | uspto-grants-1992_09 |
| ORD ID | ord-742ba7f5c9ef4e209c7da9906d644a16 |
| Source note | uspto-grants-1992_09 |