Carbon Dioxide → HCID 86746142, compound

HRID 1885944Notes

Reaction equation

HRID 1885944 reaction equation
[OH-].[Ba+2:2].[OH-].[C:4]([OH:23])(=[O:22])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]/[CH:12]=[CH:13]\[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21].C(C1C=CC=CC=1[OH:39])CCCCCCCC.[C:40](=[O:42])=[O:41]>COCCO>[C:4]([O-:23])(=[O:22])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]/[CH:12]=[CH:13]\[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21].[Ba+2:2].[C:4]([O-:23])(=[O:22])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]/[CH:12]=[CH:13]\[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21].[C:40](=[O:39])([O-:42])[O-:41]

Participants

6

Reactant 4

HCID 280Carbon DioxideHCID 67296NonylphenolHCID 445639Oleic AcidHCID 6093286Barium hydroxide

Product 1

HCID 86746142HCID 86746142, compoundYield 32%

Reagents, catalysts & solvents 1

HCID 80192-MethoxyethanolSolvent

Procedure

41 g of anhydrous barium hydroxide was slowly added to 300 g of methyl cellosolve and dissolved therein. Next, 11 g of oleic acid and a mixture of 10 g of nonyl phenol with 36 g of an alkylbenzene solvent were added thereto followed by stirring for approximately 30 minutes. Then the mixture was allowed to react while blowing carbon dioxide into the reaction system and the temperature was slowly elevated to 150° C. while removing the water thus formed. After dehydrating and removing the methyl cellosolve under reduced pressure, overbased barium oleate/carbonate (Ba=32%, metal ratio=12) was obtained as a brown viscous product.

Workup

  1. dissolutiondissolved
  2. additionwere added
  3. customto react
  4. customwas slowly elevated to 150° C.
  5. customwhile removing the water
  6. customthus formed
  7. customremoving the methyl cellosolve under reduced pressure

Sources & evidence

ORD record
ord-95a87eabaa0c460cb342b8afb861e8a9
Source dataset
uspto-grants-1992_09
Patent number
US05147917

Reaction notes

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