Dichloromethane → HCID 54399452, compound

HRID 1886111Notes

Reaction equation

HRID 1886111 reaction equation
[O:1]1[C@H:5]([C:6]2[CH:11]=[CH:10][CH:9]=[C:8]([C:12]([O:14][CH3:15])=[O:13])[CH:7]=2)[C@H:2]1[CH2:3][OH:4].C(Cl)Cl>CCCCCC.C(OCC)(=O)C>[O:1]1[C@H:5]([C:6]2[CH:11]=[CH:10][CH:9]=[C:8]([C:12]([O:14][CH3:15])=[O:13])[CH:7]=2)[C@H:2]1[CH:3]=[O:4]

Participants

4

Reactant 2

HCID 6344DichloromethaneHCID 54123376HCID 54123376, compound

Product 1

HCID 54399452HCID 54399452, compound

Reagents, catalysts & solvents 1

HCID 21226206Ethyl acetate hexaneSolvent

Procedure

The title compound is prepared analogously to Example 5a) from (2R,3R)-2,3-epoxy-3-(3-methoxycarbonylphenyl)-propanol; light-yellow oil; IR (methylene chloride): 2950, 2820, 1725, 1610, 1590, 1430, 1290, 1255 cm-1 ; Rf =0.33 (hexane/ethyl acetate 3:2).

Sources & evidence

ORD record
ord-f8fc04932ffa48538690e1cd99e2d40c
Source dataset
uspto-grants-1992_09
Patent number
US05149717

Reaction notes

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