Dichloromethane → HCID 57305581, compound

HRID 1886112Notes

Reaction equation

HRID 1886112 reaction equation
[O:1]1[C@@H:5]([C:6]2[CH:11]=[CH:10][CH:9]=[C:8]([C:12]([O:14][CH3:15])=[O:13])[CH:7]=2)[C@@H:2]1[CH2:3][OH:4].C(Cl)Cl>CCCCCC.C(OCC)(=O)C>[O:1]1[C@@H:5]([C:6]2[CH:11]=[CH:10][CH:9]=[C:8]([C:12]([O:14][CH3:15])=[O:13])[CH:7]=2)[C@@H:2]1[CH:3]=[O:4]

Participants

4

Reactant 2

HCID 6344DichloromethaneHCID 57167704HCID 57167704, compound

Product 1

HCID 57305581HCID 57305581, compound

Reagents, catalysts & solvents 1

HCID 21226206Ethyl acetate hexaneSolvent

Procedure

The title compound is prepared analogously to Example 5 from (2S,3S)-2,3-epoxy-3-(3-methoxycarbonylphenyl)-propanol; colourless oil; IR (methylene chloride): 2910, 2780, 1705, 1590, 1570, 1415, 1270, 1235 cm-1 ; Rf =0.36 (hexane/ethyl acetate 3:2).

Sources & evidence

ORD record
ord-3dec3c28c3604a4d93691f10a0eec120
Source dataset
uspto-grants-1992_09
Patent number
US05149717

Reaction notes

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