HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tolylboronic acid → 3-Methyl-5-p-tolylthiophene-2-carbaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tolylboronic acid | HCID 79799 | — |
| Reactant | 5-Bromo-3-methylthiophene-2-carbaldehyde | HCID 15115407 | — |
| Product | 3-Methyl-5-p-tolylthiophene-2-carbaldehyde | HCID 86629014 | — |
Reaction Steps
5-Bromo-3-methylthiophene-2-carbaldehyde (Spinelli, D. et al., J. Chem. Soc. Perkin Trans. 2, 1972, (12), 1866-9) was reacted with 4-methylphenylboronic acid by method J. The product with the molecular weight of 216.30 (C13H12OS) was obtained in this way; MS (ESI): 217 (M+H+).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08501771B2 |
| Source dataset | uspto-grants-2013_08 |
| ORD ID | ord-2bc2d32352d34fc7b2964fb73bda81ff |
| Source note | uspto-grants-2013_08 |