Acetic Acid → HCID 68537286, compound

Participants

Reaction Conditions

Reaction Steps

As described in Example 1 Step B]: from spiro[bicyclo[2.2.1]heptane-7,1′-cyclopentan]-2-one, 1.05 g, SeO2 (1.56 g) in acetic acid (5 ml) on heating at 120° C. for 12 h, purification crude product by flash chromatography (heptane/AcOEt 100-90%, there was obtained spiro[bicyclo[2.2.1]heptane-7,1′-cyclopentane]-2,3-dione (0.88 g) as yellow solid. MS (ESI): 196.2 (M+NH4)+.

Provenance & Evidence