HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → [(4-Bromophenyl)methyl]triphenylphosphanium bromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 4-Bromobenzyl bromide | HCID 68527 | — |
| Solvent | O-Xylene | HCID 7237 | — |
| Product | [(4-Bromophenyl)methyl]triphenylphosphanium bromide | HCID 2724858 | 156.1% |
Reaction Steps
A mixture of 1-bromo-4-(bromomethyl)benzene (5 g) and triphenylphosphine (5.24 g) in xylene (20 mL) were heated to reflux for 18 hours. The reaction mixture was cooled, filtered, washed with hexane and tried under vacuum to afford the title compound (8 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08507670B2 |
| Source dataset | uspto-grants-2013_08 |
| ORD ID | ord-7ab6c568cd874e9ba839136bde57e976 |
| Source note | uspto-grants-2013_08 |