Carbon Dioxide → Carbon Dioxide
Reaction equation
[C:1](=[O:3])=[O:2].[C:4](=[O:7])([O-:6])[O-:5]>>[C:1](=[O:3])=[O:2].[C:4](=[O:5])([OH:7])[O-:6].[C:1](=[O:5])([O-:3])[O-:2]Participants
Procedure
In still another aspect, the present invention provides a process for reducing the amount of carbon dioxide in a flue gas stream which is generated from a fossil fuel combustion system. The process includes introducing the flue gas stream and a carbonate-containing solution into an absorption column; contacting the flue gas stream with the carbonate-containing solution in the absorption column; reacting carbon dioxide in the flue gas stream with carbonate in the carbonate-containing solution to produce a carbon dioxide-, bicarbonate-, carbonate-containing solution; transferring at least a portion of heat from the carbon dioxide-, bicarbonate-, carbonate-containing solution exiting the chamber to the carbonate-containing solution such that the temperature of the chamber is from about 50° C. to about 90° C.; precipitating in a separating chamber a bicarbonate-containing solid out of the carbon dioxide-, bicarbonate-, carbonate-containing solution, wherein the separating chamber includes a carbon dioxide-, bicarbonate-, carbonate-containing solvent that has a solubility of bicarbonate in water that is less than the solubility in water of the carbon dioxide-, bicarbonate-, carbonate-containing solution in the absorption column; concentrating the bicarbonate-containing solid to form a bicarbonate-containing slurry; stripping the bicarbonate-containing slurry in a pressurized stripping column to produce a carbon dioxide product, wherein the stripping column has a pressure in the range of from 5 to 60 bar.
Workup
- customIn still another aspect, the present invention provides a process
- additionThe process includes introducing the flue gas stream
- custominto an absorption column
- additioncontaining solution
- customin the absorption column
- additionreacting carbon dioxide in the flue gas stream with carbonate in the carbonate-containing solution
Sources & evidence
- ORD record
- ord-8c8db5c6045f433d91d34ce5b2bc82d3
- Source dataset
- uspto-grants-2013_08
- Patent number
- US08512445B2
Reaction notes
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