HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbazole → HCID 68603418, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbazole | HCID 6854 | — |
| Reactant | Potassium Phosphate, Tribasic | HCID 62657 | — |
| Reactant | 1,4-Dibromonaphthalene | HCID 66521 | — |
| Reactant | Hexanediamine | HCID 134940 | — |
| Catalyst | Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI) | HCID 24350 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | HCID 68603418 | HCID 68603418 | 6% |
Reaction Steps
As depicted in Reaction 6, a solution of 10 g (31.3 mmol) of carbazole, 13.5 g (31.3 mmol) of 1,4-dibromonaphthalene, CuI, diaminohexane and K3PO4 in dioxane was refluxed for 15 hours. After completion of the reaction, the reaction mixture was extracted with ethyl acetate. After the solvent was removed under reduced pressure, the residue was purified by column chromatography to give the title compound. The product was collected by filtration under reduced pressure and dried. Yield: 6%. MS (EI) (Calcd. for C34H22BrN: 523.09. Found: 523).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08512877B2 |
| Source dataset | uspto-grants-2013_08 |
| ORD ID | ord-da1f874af74444b19b1abdb3246d5ef8 |
| Source note | uspto-grants-2013_08 |