2-Bromo-7-iodo-9,9-dimethyl-9H-fluorene → 2-(7-Bromo-9,9-dimethylfluoren-2-yl)dibenzofuran

HRID 1893112Notes

Reaction equation

HRID 1893112 reaction equation
BrC1C=CC([C:8]2[CH:20]=[CH:19][C:11]3[O:12][C:13]4[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=4[C:10]=3[CH:9]=2)=CC=1.[Br:21][C:22]1[CH:34]=[CH:33][C:32]2[C:31]3[C:26](=[CH:27][C:28](I)=[CH:29][CH:30]=3)[C:25]([CH3:37])([CH3:36])[C:24]=2[CH:23]=1>>[Br:21][C:22]1[CH:23]=[C:24]2[C:32]([C:31]3[CH:30]=[CH:29][C:28]([C:8]4[CH:20]=[CH:19][C:11]5[O:12][C:13]6[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=6[C:10]=5[CH:9]=4)=[CH:27][C:26]=3[C:25]2([CH3:37])[CH3:36])=[CH:33][CH:34]=1

Participants

3

Reactant 2

HCID 453821792-Bromo-7-iodo-9,9-dimethyl-9H-fluoreneHCID 590220832-(4-Bromophenyl)dibenzo[b,d]furan

Product 1

HCID 598664642-(7-Bromo-9,9-dimethylfluoren-2-yl)dibenzofuran

Procedure

2-(7-bromo-9,9-dimethylfluoren-2-yl)dibenzofuran was synthesized in the same manner as in the synthesis of 2-(4-bromophenyl)dibenzofuran except that 2-bromo-7-iodo-9,9-dimethylfluorene was used instead of 4-bromoiodobenzene.

Sources & evidence

ORD record
ord-066e5014fcdf45b3b5ed01cf478b72c4
Source dataset
uspto-grants-2013_08
Patent number
US08512875B2

Reaction notes

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