Methyl 1-hydroxy-1-cyclopropane carboxylate → 1-Sulfamoyloxy-cyclopropanecarboxylic acid methyl ester

HRID 1893643Notes

Reaction equation

HRID 1893643 reaction equation
C1([O:7][S:8](=O)(=[O:10])[NH2:9])C=CC=CC=1.[CH3:12][O:13][C:14]([C:16]1([OH:19])[CH2:18][CH2:17]1)=[O:15]>>[CH3:12][O:13][C:14]([C:16]1([O:19][S:8](=[O:10])(=[O:7])[NH2:9])[CH2:18][CH2:17]1)=[O:15]

Participants

3

Reactant 2

HCID 2733178Methyl 1-hydroxy-1-cyclopropane carboxylateHCID 11030308Phenylsulfamate

Product 1

HCID 574451521-Sulfamoyloxy-cyclopropanecarboxylic acid methyl ester

Procedure

1-Sulfamoyloxy-cyclopropanecarboxylic acid methyl ester was synthesized according to the method presented in the synthesis of sulfamic acid phenyl ester in Example 1 with the exception of utilizing 1-hydroxy-cyclopropanecarboxylic acid methyl ester to obtain 1-Sulfamoyloxy-cyclopropanecarboxylic acid methyl ester.

Workup

  1. custom1-Sulfamoyloxy-cyclopropanecarboxylic acid methyl ester was synthesized

Sources & evidence

ORD record
ord-1796a62d267c4d95a72df119bf1e2ec2
Source dataset
uspto-grants-2013_08
Patent number
US08513186B2

Reaction notes

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