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HRID1896229

反应详情

EQUATION

反应方程式

HRID 1896229 的结构方程式

REACTANTS

反应物

2
结构：O=[N+]([O-])c1cc(-n2cc(CCCC#Cc3cccc(CNc4nc(Cl)nc5c4ncn5[C@H]4[C@H](O)[C@H](O)[C@@H]5C[C@@H]54)c3)nn2)ccc1F
HCID86672494

未命名化合物

结构：C#CCCCCC#Cc1cccc(CNc2nc(Cl)nc3c2ncn3[C@H]2[C@H](O)[C@H](O)[C@@H]3C[C@@H]32)c1
HCID86672497

未命名化合物

PRODUCTS

生成物

1
结构：O=[N+]([O-])c1cc(-n2cc(CCCCC#Cc3cccc(CNc4nc(Cl)nc5c4ncn5[C@H]4[C@H](O)[C@H](O)[C@@H]5C[C@@H]54)c3)nn2)ccc1F
HCID86672496

未命名化合物

收率 95%

PROCEDURE

实验过程

Compound 215 (95%) was synthesized from compound 212 following the same procedure as for compound 214. 1H NMR (CDCl3, 400 MHz) δ 8.44-8.39 (m, 1H), 8.07-8.11 (m, 1H), 7.83 (s, 1H), 7.77 (s, 1H), 7.51-7.43 (m, 2H), 7.33-7.26 (m, 3H), 6.58 (br s, 1H), 4.87 (s, 1H), 4.79 (br s, 2H), 4.15 (s, 1H), 4.02 (d, J=6.8 Hz, 1H), 2.89 (t, J=7.6 Hz, 2H), 2.49 (t, J=6.8 Hz, 2H), 2.08-2.04 (m, 1H), 1.96-1.90 (m, 2H), 1.76-1.64 (m, 3H), 1.31-1.28 (m, 1H), 0.79-0.85 (m, 1H). HRMS calculated for C32H30ClFN9O4 (M+H)+: 658.2093. Found 658.2124.