HuagongsheHuagongshe Chemistry Print Report · For research reference only
(2R,4S,5S)-5-Azido-2-benzhydryl-tetrahydropyran-4-ol → (2R,4S,5S)-5-amino-2-benzhydryl-tetrahydropyran-4-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (2R,4S,5S)-5-Azido-2-benzhydryl-tetrahydropyran-4-ol | HCID 11681112 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | (2R,4S,5S)-5-amino-2-benzhydryl-tetrahydropyran-4-ol | HCID 11594377 | 100.8% |
Reaction Steps
(2R,4S,5S)-5-Azido-2-benzhydryl-tetrahydropyran-4-ol (0.05 g, 0.14 mmol) was hydrogenated (Procedure G) to yield (2R,4S,5S)-5-amino-2-benzhydryl-tetrahydropyran-4-ol 0.04 g (97%, [α]D=(+) 66.2, c=1, MeOH).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08519159B2 |
| Source dataset | uspto-grants-2013_08 |
| ORD ID | ord-827b555edfde46e1ba0fb6eb9dec59c2 |
| Source note | uspto-grants-2013_08 |