HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetone → 1,3-Dioxane-5-methanol, 5-ethyl-2,2-dimethyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetone | HCID 180 | — |
| Reactant | Glycerol | HCID 753 | — |
| Reactant | Trimethylolpropane | HCID 6510 | — |
| Reactant | 6-Undecanone | HCID 13561 | — |
| Solvent | Hexane | HCID 8058 | — |
| Product | 1,3-Dioxane-5-methanol, 5-ethyl-2,2-dimethyl- | HCID 11816152 | — |
Reaction Steps
The same procedures as in Production Example 3 are carried out except that glycerol is replaced with 292.1 g (2.18 mol) of trimethylolpropane, 6-undecanone is replaced with 474.0 g (8.17 mol) of acetone, and the amount of paratoluenesulfonic acid monohydrate is changed to 6.0 g (0.0315 mol) and the amount of hexane is changed to 900 ml to give 5-hydroxymethyl-5-ethyl-2,2-dimethyl-1,3-dioxane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05575944 |
| Source dataset | uspto-grants-1996_11 |
| ORD ID | ord-0bcca7a3acd64bb0a6c7cfc003e36774 |
| Source note | uspto-grants-1996_11 |