Ethanol → Sodium 4-allyloxyphenylsulfonate

HRID 1901809Notes

Reaction equation

HRID 1901809 reaction equation
[C:1]1([S:7]([O-:10])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Na+:11].[CH2:12](Br)[CH:13]=[CH2:14].C([OH:18])C>[OH-].[Na+]>[CH2:12]([O:18][C:4]1[CH:5]=[CH:6][C:1]([S:7]([O-:10])(=[O:9])=[O:8])=[CH:2][CH:3]=1)[CH:13]=[CH2:14].[Na+:11]

Participants

5

Reactant 3

HCID 702EthanolHCID 7841Allyl bromideHCID 517327Sodium benzenesulfonate

Product 1

HCID 86748076Sodium 4-allyloxyphenylsulfonate

Reagents, catalysts & solvents 1

HCID 14798Sodium HydroxideSolvent

Procedure

30 g of sodium phenylsulfonate are dissolved in 60 ml of ethanol and 50 ml of 15% sodium hydroxide, 20 g of allyl bromide are added and the mixture is refluxed for 48 hours. The ethanol is concentrated and the precipitate obtained is filtered off and then dried under vacuum in the presence of phosphorus pentoxide to give 23.3 g of the expected product.

Workup

  1. temperaturethe mixture is refluxed for 48 hours
  2. concentrationThe ethanol is concentrated
  3. customthe precipitate obtained
  4. filtrationis filtered off
  5. dry with materialdried under vacuum in the presence of phosphorus pentoxide

Sources & evidence

ORD record
ord-31c96035e4474bd48ec302906ebcd9fc
Source dataset
uspto-grants-1996_11
Patent number
US05578633

Reaction notes

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