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HRID1902131

反应详情

EQUATION

反应方程式

HRID 1902131 的结构方程式

REACTANTS

反应物

2
结构：CN1C(C)(C)CC(O)CC1(C)C
HCID75472

1,2,2,6,6-Pentamethylpiperidin-4-ol

C10H21NO

结构：COC(=O)NNC(=O)OC
HCID265934

dimethyl hydrazine-1,2-dicarboxylate

C4H8N2O4

PRODUCTS

生成物

1
结构：CN1C(C)(C)CC(OC(=O)NNC(=O)OC2CC(C)(C)N(C)C(C)(C)C2)CC1(C)C
HCID53819262

未命名化合物

收率 38.6%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-].[Ti+4]
催化剂HCID21801

Titanium(IV) n-butoxide

C16H36O4Ti

PROCEDURE

实验过程

The procedure of Example 1 is repeated using 33.9 g of 1,2,2,6,6-pentamethylpiperidin-4-ol, 13.3 g of dimethyl hydrazine-1,2-dicarboxylate and 0.31 g of tetrabutyl titanate to afford 14.8 g of the title compound as a white solid; mp 189°-191° C.