Iodo benzene diacetate → HCID 53750351, compound

HRID 1902136Notes

Reaction equation

HRID 1902136 reaction equation
[NH:1]([C:23]([O:25][CH:26]1[CH2:31][C:30]([CH3:33])([CH3:32])[N:29]([O:34][CH:35]2[CH2:40][CH2:39][CH2:38][CH2:37][CH2:36]2)[C:28]([CH3:42])([CH3:41])[CH2:27]1)=[O:24])[NH:2][C:3]([O:5][CH:6]1[CH2:11][C:10]([CH3:13])([CH3:12])[N:9]([O:14][CH:15]2[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]2)[C:8]([CH3:22])([CH3:21])[CH2:7]1)=[O:4].C(O)(=O)C.C(O)(=O)C.IC1C=CC=CC=1>>[N:2]([C:3]([O:5][CH:6]1[CH2:7][C:8]([CH3:22])([CH3:21])[N:9]([O:14][CH:15]2[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]2)[C:10]([CH3:13])([CH3:12])[CH2:11]1)=[O:4])=[N:1][C:23]([O:25][CH:26]1[CH2:27][C:28]([CH3:41])([CH3:42])[N:29]([O:34][CH:35]2[CH2:36][CH2:37][CH2:38][CH2:39][CH2:40]2)[C:30]([CH3:32])([CH3:33])[CH2:31]1)=[O:24]

Participants

3

Reactant 2

HCID 12217721Iodo benzene diacetateHCID 54341087Bis(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) Hydrazine-1,2-dicarboxylate

Product 1

HCID 53750351HCID 53750351, compoundYield 84.7%

Procedure

The procedure of Example 4 is repeated using 12.2 g of bis(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) hydrazine-1,2-dicarboxylate and 7.2 g of iodobenzene diacetate to afford 10.3 g of the title compound; mp 189°-19 1° C.

Sources & evidence

ORD record
ord-525d7d8e212d4cb98a56b7dede99d579
Source dataset
uspto-grants-1996_11
Patent number
US05578731

Reaction notes

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