Azido(trimethyl)stannane → HCID 178451571, compound

Participants

Reaction Steps

To a solution of the title compound from Step A (298 mg, 0.96 mmol) in toluene was added trimethylstannyl azide (787 mg, 3.84 mmol). The mixture was refluxed for 18 hours and then cooled and 1N HCL was added. The aqueous layer was extracted with ethyl acetate (3×1 vol) and the organic layer was washed with water, brine, dried over magnesium sulfate and concentrated. Purification by MPLC (LH20 column methanol) provided the title compound (214 mg, 0.60 mmol).

Provenance & Evidence