HuagongsheHuagongshe Chemistry Print Report · For research reference only
Pyridine → HCID 86738663, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Pyridine | HCID 1049 | — |
| Reactant | cis-3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropylcarbonyl chloride | HCID 12617358 | — |
| Reactant | HCID 70476518 | HCID 70476518 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 86738663 | HCID 86738663 | 89.4% |
Reaction Steps
In the manner of Example 4, the reaction of 1.00 g (0.004 mole) of trans-3-[(3-fluorophenyl)methyl]-1-indanol (98% trans, 2% cis) and 0.93 g (0.004 mole) of cis-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarbonyl chloride in the presence of 0.32 g (0.004 mole) of pyridine and 50 mL of toluene gave 1.55 g of trans-3-[(3-fluorophenyl)methyl]-1-indanyl cis-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate. The ir and nmr spectra were consistent with the proposed structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04362744 |
| Source dataset | uspto-grants-1982_12 |
| ORD ID | ord-c7159ce534744ef598a44548fe9dbf5b |
| Source note | uspto-grants-1982_12 |