4-Chlorobenzenesulfenylchloride → HCID 131712906, compound

Participants

Reaction Steps

2-Thiocyanomethylthio-4,4-dimethyl-5-methylenethiazoline, 4.0 gm (prepared in a manner consistent with Examples 1 and 2) was added to 100 ml of dichloromethane. 3.11 gm of 4-chlorophenylthiochloride was added to the system. The system was stirred at room temperature for 48 hours. The product precipitated from solution. The product was filtered and air-dried to give 4.7 gm of the 2-thiocyanomethylthio-4,4-dimethyl-5-(4-chlorophenylthio)methylenethiazoline as an off-white solid, m.p. 122°-131° C. Listed as compound number 1 in Table I.

Provenance & Evidence