HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,12-Dodecanediamine → N-[1-(Methylamino)-2-nitroethenyl]-1,12-dodecanediamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,12-Dodecanediamine | HCID 17727 | — |
| Reactant | 1-Methylthio-1-methylamino-2-nitroethylene | HCID 123549 | — |
| Solvent | Water | HCID 962 | — |
| Product | N-[1-(Methylamino)-2-nitroethenyl]-1,12-dodecanediamine | HCID 86737710 | 60% |
Reaction Steps
A mixture of 1,12-diaminododecane (3 g) and N-methyl-1-(methylthio)-2-nitroethenamine (1.48 g) in water (50 ml) was stirred at room temperature for 20 hours. The solution was evaporated in vacuo and the residue chromatographed (silica/methanol). The appropriate eluate was evaporated to yield the title compound (1.8 g), mp. 123°-125°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04366164 |
| Source dataset | uspto-grants-1982_12 |
| ORD ID | ord-528e3df869bd4d94afb30b7acd4fe29e |
| Source note | uspto-grants-1982_12 |