Vinyl Chloride → HCID 86738716, compound

HRID 1902889Notes

Reaction equation

[CH:1]([Cl:3])=[CH2:2].C(OC([O:10][O:11][C:12]([O:14][CH:15]([CH3:17])[CH3:16])=[O:13])=O)(C)C>>[C:15]([O:14][C:12]([O:11][O-:10])=[O:13])([CH3:17])([CH3:1])[CH3:16].[CH:1]([Cl:3])=[CH2:2]

Participants

Reactant 2

HCID 6338Vinyl Chloride2×

HCID 7769Diisopropyl peroxydicarbonate

Product 1

HCID 86738716HCID 86738716, compound

Procedure

Into an autoclave of 300 ml capacity made of stainless steel, there were charged 0.6 g of BPAC of 94% purity, 29.4 g of vinyl chloride (hereinafter referred to as VCL) of 100% purity and 0.01 g of diisopropylperoxydicarbonate of 99% purity and further 100 ml of 0.2% aqueous solution of polyvinyl alcohol (degree of saponification 89%). After the atmospheric environment in the autoclave was replaced with nitrogen, polymerization was carried out at 52° C. for 6 hours.

Workup

customAfter the atmospheric environment in the autoclave was replaced with nitrogen, polymerization

Sources & evidence

ORD record: ord-ecd3b6deaa684d23a32df3acc5f625bf
Source dataset: uspto-grants-1982_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04366290

Reaction notes

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