Sodium Methoxide → HCID 123797137, compound

HRID 1902900Notes

Reaction equation

HRID 1902900 reaction equation
[CH3:1][SiH:2]([CH3:13])[C:3]1[CH:12]=[CH:11][C:6]([O:7][SiH](C)C)=[CH:5][CH:4]=1.C[O-].[Na+]>C(OCC)C.CO>[CH3:1][SiH:2]([CH3:13])[C:3]1[CH:12]=[CH:11][C:6]([OH:7])=[CH:5][CH:4]=1

Participants

5

Reactant 2

HCID 10942334Sodium MethoxideHCID 123554066HCID 123554066, compound

Product 1

HCID 123797137HCID 123797137, compound

Reagents, catalysts & solvents 2

HCID 887MethanolSolventHCID 3283Diethyl EtherSolvent

Procedure

To a cold solution (~9° C.) of 26.0 g of 4-dimethylsilylphenoxydimethylsilane in 250 ml of diethylether was added 10 ml of a solution of sodium methoxide (0.4 N) in methanol and the mixture stirred overnight. Solvents were removed by evaporation on a rotary evaporator at room temperature to yield 15.6 g (83.0%) of crude product, m.p. 59°-60° C. After recrystallization from hexane, the phenol was obtained as needles, m.p. 61° C.

Workup

  1. customSolvents were removed by evaporation on a rotary evaporator at room temperature
  2. customto yield 15.6 g (83.0%) of crude product, m.p. 59°-60° C
  3. customAfter recrystallization from hexane

Sources & evidence

ORD record
ord-53cd8e44920a4b94a04fedfc09a60ae9
Source dataset
uspto-grants-1982_12
Patent number
US04366323

Reaction notes

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