Benzoin → HCID 86743110, compound

HRID 1904426Notes

Reaction equation

HRID 1904426 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([S:10](Cl)(=[O:12])=[O:11])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[C:14]1([C:20]([CH:22]([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[OH:23])=[O:21])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C(C(C)=O)C.[OH-].[Na+]>[N+:1]([C:4]1[CH:5]=[C:6]([S:10]([OH:12])(=[O:21])=[O:11])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[C:14]1([C:20]([CH:22]([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[OH:23])=[O:21])[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

Participants

5

Reactant 2

HCID 8400BenzoinHCID 84763-Nitrobenzenesulfonyl chloride

Product 1

HCID 86743110HCID 86743110, compound

Reagents, catalysts & solvents 2

HCID 6569Methyl Ethyl KetoneSolventHCID 14798Sodium HydroxideSolvent

Procedure

In accordance with the procedure of Example 2, 3-nitrobenzenesulfonyl chloride is reacted with benzoin in methyl ethyl ketone and aqueous NaOH. The resultant sulfonate melts at 92°-96° C.

Sources & evidence

ORD record
ord-6da48bb161e2437282d92454a437b4d8
Source dataset
uspto-grants-1989_06
Patent number
US04837350

Reaction notes

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