Methyl iodide → HCID 20039280, compound

HRID 1904497Notes

Reaction equation

[F:1][C:2]([F:31])([F:30])[C:3]1[CH:4]=[C:5]([P:9]([C:20]2[CH:25]=[CH:24][CH:23]=[C:22]([C:26]([F:29])([F:28])[F:27])[CH:21]=2)[C:10]2[CH:15]=[CH:14][CH:13]=[C:12]([C:16]([F:19])([F:18])[F:17])[CH:11]=2)[CH:6]=[CH:7][CH:8]=1.[CH3:32][I:33]>>[I-:33].[CH3:32][P+:9]([C:5]1[CH:6]=[CH:7][CH:8]=[C:3]([C:2]([F:1])([F:30])[F:31])[CH:4]=1)([C:20]1[CH:25]=[CH:24][CH:23]=[C:22]([C:26]([F:29])([F:27])[F:28])[CH:21]=1)[C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([C:16]([F:18])([F:19])[F:17])[CH:11]=1

Participants

Reactant 2

HCID 6328Methyl iodide

HCID 427977Phosphine, tris[3-(trifluoromethyl)phenyl]-

Product 1

HCID 20039280HCID 20039280, compoundYield 82.5%

Procedure

Starting from 2.39 g (5.13 mmol) of tris(3-trifluoromethylphenyl)phosphine and 1.10 g (7.75 mmol, 1.51 eq) of methyl iodide, 2.57 g (4.23 mmol, 82.4%) of methyltris(3-trifluoromethylphenyl)phosphonium iodide was obtained: mp 225.1°-229.3° C. (dec);

Sources & evidence

ORD record: ord-3ea3e77158164ef8b9f5a63abe2af5fd
Source dataset: uspto-grants-1989_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04837391

Reaction notes

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