Acetic Anhydride → Butyrate

HRID 1904764Notes

Reaction equation

HRID 1904764 reaction equation
C(OC(=O)C)(=O)C.[C:8]([OH:15])(=[O:14])[CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]>>[C:8]([O-:15])(=[O:14])[CH2:9][CH2:10][CH3:11].[C:8]([O-:15])(=[O:14])[CH2:9][CH2:10][CH2:11][CH3:12].[C:8]([O-:15])(=[O:14])[CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

Participants

5

Reactant 2

HCID 7918Acetic AnhydrideHCID 8892Hexanoic Acid

Product 3

HCID 104775ButyrateHCID 114781ValerateHCID 4398339Hexanoate

Procedure

In a manner similar to that set forth in Paragraph A, but substituting for acetic anhydride, the anyhydrides or halides of proprionic, butanoic, pentanoic, or hexanoic acid, the corresponding manoalide δ-lactone proprionate, butanoate, pentanoate, and hexanoate are prepared.

Sources & evidence

ORD record
ord-945b4efe454f45bda7a6e986f124f8aa
Source dataset
uspto-grants-1989_06
Patent number
US04839385

Reaction notes

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