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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1904806Generated: November 3, 2026

Styrene → Prop-2-enenitrile--ethenylbenzene (1/1)

https://huagongshe.com/reaction/1904806

Reaction equation

Participants

RoleNameHCIDCharge
ReactantStyreneHCID 7501—
ReactantAcrylonitrileHCID 7855—
Reactant1-DodecanethiolHCID 8195—
ProductProp-2-enenitrile--ethenylbenzene (1/1)HCID 62696—

Reaction Steps

A graft precursor was prepared by following the procedure of Example 13, except that a mixed monomer consisting of 210 g of styrene, 90 g of acrylonitrile, and 0.6 g of n-dodecyl mercaptan as a molecular weight regulator was used in the place of 300 g of styrene. Separately, an acrylonitrile-styrene copolymer was obtained by placing a mixed solution consisting of 70 g of styrene, 30 g of acrylonitrile, 0.2 g of n-dodecyl mercaptan, and 0.5 g benzoyl peroxide in 500 g of an aqueous 1% polyvinyl alcohol solution and holding the resultant mixture at a temperature of 80° to 85° C. for seven hours to complete polymerization. Graft resin compositions were produced by following the procedure of Example 13, except that the amounts of the copolymer, the graft precursor mentioned above, the propylene polymer to be mixed were varied as indicated in Table 7. The results were as shown in Table 7.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04839423
Source datasetuspto-grants-1989_06
ORD IDord-b2265d40bb0143b98ca940f20d20198d
Source noteuspto-grants-1989_06