HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aniline → HCID 2797953, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aniline | HCID 6115 | — |
| Reactant | Dimethyl acetylenedicarboxylate | HCID 12980 | — |
| Solvent | 1,2-Dichloroethane | HCID 11 | — |
| Product | HCID 2797953 | HCID 2797953 | — |
Reaction Steps
To a stirred solution of dimethylacetylenedicarboxylate (DMAD, 0.10 mol) in 50 mL of ethylene dichloride (EDC), is slowly added a solution of aniline (0.10 mol) in 15 mL of EDC. The temperature of the reaction mixtures is maintained below 30° C. and stirring is continued for about one hour until the reaction is essentially complete. The EDC is then removed under vacuum to afford the dimethyl 3-phenylaminobut-2-ene-dioate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04843162 |
| Source dataset | uspto-grants-1989_06 |
| ORD ID | ord-5c175b57db4446ab860dc496396a8ff3 |
| Source note | uspto-grants-1989_06 |