HuagongsheHuagongshe Chemistry Print Report · For research reference only
5-(p-Methoxybenzylidene)-hydantoin → 5-(4-Methoxy-benzyl)-hydantoin
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5-(p-Methoxybenzylidene)-hydantoin | HCID 94749 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Sodium Hydroxide | HCID 14798 | — |
| Product | 5-(4-Methoxy-benzyl)-hydantoin | HCID 95727 | 82% |
Reaction Steps
218.2 g (1 mole) of 5-(4-methoxy-benzylidene)-hydantoin are dissolved in 2 l of a N sodium hydroxide solution and 50 g of wet Raney-nickel are added. The reaction mixture is worked up according to Example 6. Thus 180.6 g of the desired compound are obtained, yield 82 %. Mp.: 174° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04647694 |
| Source dataset | uspto-grants-1987_03 |
| ORD ID | ord-3bdb2291c15f4aa781b7fd3ae40a6099 |
| Source note | uspto-grants-1987_03 |