HRID1906250

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14798

Sodium Hydroxide

HNaO

HCID4329331

未命名化合物

HCID17993396

2-[Bis[2-(dodecyloxy)ethyl]amino]ethanol

C30H63NO3

PRODUCTS

生成物

结构：CCCCCCCCCCCCOCCN(CCOCCCCCCCCCCCC)CCOCCCCCCCCCCCC

HCID20041967

2-(Dodecyloxy)-N,N-bis[2-(dodecyloxy)ethyl]ethanamine

C42H87NO3

收率 116.5%

PROCEDURE

实验过程

20 grams (0.042 mole) of di-(lauryloxyethyl)-hydroxyethyl amine (the second fraction recovered in Example 12) were reacted with 2.0 grams (0.05 mole) of sodium hydroxide and 12.1 grams (0.042 mole) of lauryl sulfate, Na salt using the procedure of Example 12. Purification of the product again using the procedure of Example 12, gave 32 grams of a yellow oily product having an amine number of 85.6.

WORKUP

后处理

customPurification of the product

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e1b2328b4ee74c6a954e131200e875a2
来源数据集: uspto-grants-1987_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04650865
来源说明: uspto-grants-1987_03

反应 SMILES

[CH2:1]([O:13][CH2:14][CH2:15][N:16]([CH2:20][CH2:21][O:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH2:17][CH2:18][OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[OH-].[Na+].S([O-])(O[CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52])(=O)=O>>[CH2:52]([O:19][CH2:18][CH2:17][N:16]([CH2:20][CH2:21][O:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH2:15][CH2:14][O:13][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[CH2:51][CH2:50][CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH2:44][CH2:43][CH2:42][CH3:41]