HuagongsheHuagongshe Chemistry Print Report · For research reference only
6-(5-Cholesten-3beta-yloxy)hexyl iodide → 17beta-Carbomethoxy-androst-5-en-3beta-yl 6-iodohexyl ether
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 6-(5-Cholesten-3beta-yloxy)hexyl iodide | HCID 12805525 | — |
| Reactant | 6-(17beta-carbomethoxy-androst5-en-3beta-yloxy)-hexyl 1-thio-beta-D-mannopyranoside | HCID 86741364 | — |
| Product | 17beta-Carbomethoxy-androst-5-en-3beta-yl 6-iodohexyl ether | HCID 67945410 | — |
Reaction Steps
Employing the procedure substantially as described in Example 2, but substituting for cholest-5-en-3β-yl 6-iodohexyl ether, an equivalent amount of 17β-carbomethoxy-androst-5-en-3β-yl 6-iodohexyl ether, there was prepared 6-(17β-carbomethoxy-androst-5-en-3β-yloxy)-hexyl 1-thio-β-D-mannopyranoside (Step D). TLC data and Rf values are given in the above Table.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04652553 |
| Source dataset | uspto-grants-1987_03 |
| ORD ID | ord-06147327074c4675b15d34d8794de4c6 |
| Source note | uspto-grants-1987_03 |