HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thionyl Chloride → 4-(2-Oxopropyl)benzoyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 4-(2-Oxopropyl)benzoic acid | HCID 576244 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 4-(2-Oxopropyl)benzoyl chloride | HCID 20134178 | — |
Reaction Steps
Thionyl chloride (1.45 ml) was added to 4-acetonylbenzoic acid (3.56 g) in benzene and the mixture refluxed for 1 hour. Benzene was evaporated to give the title compound as a yellow oil, 2.61 g, (bp 135°-140°/0.5 mm). γ(CDCl3) 7.78 (3H, s), 6.17 (2H, s), 2.63 (2H, d, J=9 Hz), 1.88 (2H, d, J=9 Hz).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04654371 |
| Source dataset | uspto-grants-1987_03 |
| ORD ID | ord-90e15fd66dd34389bc5941277f747f54 |
| Source note | uspto-grants-1987_03 |