1-Adamantanecarbonyl chloride → Benzyltrimethylammonium 1,1,3,3,3-pentafluoro-2-(adamantane-1-carbonyloxy)propanesulfonate
Reaktionsgleichung
[F:1][C:2]([F:13])([S:9]([O-:12])(=[O:11])=[O:10])[CH:3]([OH:8])[C:4]([F:7])([F:6])[F:5].[CH2:14]([N+:21]([CH3:24])([CH3:23])[CH3:22])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[C:25]12([C:35](Cl)=[O:36])[CH2:34][CH:29]3[CH2:30][CH:31]([CH2:33][CH:27]([CH2:28]3)[CH2:26]1)[CH2:32]2>>[C:25]12([C:35]([O:8][CH:3]([C:4]([F:6])([F:5])[F:7])[C:2]([F:1])([F:13])[S:9]([O-:12])(=[O:10])=[O:11])=[O:36])[CH2:32][CH:31]3[CH2:30][CH:29]([CH2:28][CH:27]([CH2:33]3)[CH2:26]1)[CH2:34]2.[CH2:14]([N+:21]([CH3:24])([CH3:23])[CH3:22])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1Komponenten
3
Versuchsvorschrift
Benzyltrimethylammonium 1,1,3,3,3-pentafluoro-2-hydroxypropane-1-sulfonate in Synthesis Example 1-1 and 1-adamantanecarboxylic acid chloride were reacted in accordance with the teaching of JP-A 2008-106045, yielding the desired compound, benzyltrimethylammonium 2-(adamantane-1-carbonyloxy)-1,1,3,3,3-pentafluoropropane-1-sulfonate as white crystals.
Aufarbeitung
- custom