Triacetoxyperiodinane → HCID 59737228, compound

Participants

Reaction Steps

A suspension of alcohol 190 (0.178 g, 0.463 mmol) in DCM (5.0 mL) was treated with solid Dess-Martin periodinane (0.399 g, 0.94 mmol) and stirred under nitrogen atmosphere at room temperature for 20 h. The reaction mixture was quenched with an aqueous solution of Na2S2O3, stirred for 60 min, diluted with DCM/MeOH mixture, washed with saturated NaHCO3, dried over MgSO4, filtered and concentrated to give title compound 191 (0.155 g, 88% yield).

Provenance & Evidence