Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Dimethylacetamide | HCID 31374 | — |
| Reactant | Ethyl 2-methyl-3,5-dinitrobenzoate | HCID 43386560 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 57470203 | HCID 57470203 | 48% |
Reaction Steps
A mixture of ethyl 2-methyl-3,5-dinitrobenzoate (35 g, 0.14 mol) and DMA (32 g, 0.27 mol) in DMF (200 mL) was heated at 100° C. for 5 h. The mixture was poured into ice-water and the precipitated solid was filtered and washed with water to give (E)-ethyl 2-(2-(dimethylamino)vinyl)-3,5-dinitrobenzoate (11 g, 48%)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US08598181B2 |
|---|
| Source dataset | uspto-grants-2013_12 |
|---|
| ORD ID | ord-8422be8cf1034910802724e20a74ff4f |
|---|
| Source note | uspto-grants-2013_12 |
|---|
