Aluminium lithium hydride → HCID 68997774, compound

HRID 1909797Notes

Reaction equation

HRID 1909797 reaction equation
C([O:3][C:4](=O)[C:5]1[CH:10]=[CH:9][C:8]([O:11][C:12]2[CH:17]=[CH:16][C:15]([C:18]3[CH:22]=[CH:21][S:20][CH:19]=3)=[CH:14][CH:13]=2)=[CH:7][CH:6]=1)C.[H-].[H-].[H-].[H-].[Li+].[Al+3]>>[S:20]1[CH:21]=[CH:22][C:18]([C:15]2[CH:16]=[CH:17][C:12]([O:11][C:8]3[CH:9]=[CH:10][C:5]([CH2:4][OH:3])=[CH:6][CH:7]=3)=[CH:13][CH:14]=2)=[CH:19]1

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 69002537HCID 69002537, compound

Product 1

HCID 68997774HCID 68997774, compoundYield 99%

Procedure

The title compound (300 mg, 99%) was prepared from the product of step 3 (0.35 g, 1.1 mmol) and LiAlH4 (82 mg, 2.2 mmol) using the procedure of Example 156, step 2.

Sources & evidence

ORD record
ord-72c5648a0816449c860bcaf941a77bc6
Source dataset
uspto-grants-2013_12
Patent number
US08598359B2

Reaction notes

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