HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Dimethoxyethane → HCID 59359504, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,2-Dimethoxyethane | HCID 8071 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Phenylboronic Acid | HCID 66827 | — |
| Reactant | HCID 86093998 | HCID 86093998 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 59359504 | HCID 59359504 | — |
Reaction Steps
10.2 g (0.051 mol) of 2-bromo-3,4,5-trimethylpyridine was mixed with 7.86 g (0.061 mol) of phenylboronic acid, 1.8 g (0.0016 mol) of Pd(Ph3)4, 19.1 g (0.13 mol) of K2CO3 50 mL of DME and 50 mL of water. The reaction mixture was refluxed for 20 hours and separated on silica gel column. MS confirmed the desired product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08603645B2 |
| Source dataset | uspto-grants-2013_12 |
| ORD ID | ord-f7fc82e5b5484a158ca3180e2063cce3 |
| Source note | uspto-grants-2013_12 |