Toluene → HCID 17801484, compound

HRID 1911713Notes

Reaction equation

HRID 1911713 reaction equation
[C:1]1([CH3:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:8]1(=[O:14])[O:13][C:11](=[O:12])[CH:10]=[CH:9]1>>[C:1]1([CH3:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:11]1(=[O:12])[O:13][C:8](=[O:14])[CH:9]=[CH:10]1

Participants

3

Reactant 2

HCID 1140TolueneHCID 7923Maleic Anhydride2×

Product 1

HCID 17801484HCID 17801484, compound

Conditions

Temperature
180 °C

Procedure

125 g (1.36 moles) of toluene and 13.3 g (0.136 moles) of maleic anhydride were weighed into a 300 ml Parr reactor. The reactor was heated to 180° C. then pressurized to 60 psi with air to initiate maleic anhydride free radical formation. The solution was stirred at 180° C. for 4 hr. The reactor was cooled to room temperature, and then the contents were transferred to a round bottom flask. The toluene and maleic anhydride were removed with a rotary evaporator. Weight of residue was 1.4 g.

Workup

  1. temperatureThe reactor was cooled to room temperature
  2. customthe contents were transferred to a round bottom flask
  3. customThe toluene and maleic anhydride were removed with a rotary evaporator

Sources & evidence

ORD record
ord-eae7501695ef4a36bb2a20400b19912f
Source dataset
uspto-grants-2013_12
Patent number
US08604110B2

Reaction notes

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