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HRID1912661

反应详情

EQUATION

反应方程式

HRID 1912661 的结构方程式

REACTANTS

反应物

2
结构：C[C@]12CCCCC1[C@@H](O[N+](=O)[O-])C[C@@H]1[C@@H]2CC[C@@]2(C)[C@H]1CC13OCCOC12OCCO3
HCID86635563

未命名化合物

结构：C[C@]12CCCCC1[C@H](O)C[C@@H]1[C@@H]2CC[C@@]2(C)[C@H]1CC13OCCOC12OCCO3
HCID86651493

未命名化合物

PRODUCTS

生成物

1
结构：C[C@]12CCCCC1[C@H](O[N+](=O)[O-])C[C@@H]1[C@@H]2CC[C@@]2(C)[C@H]1CC13OCCOC12OCCO3
HCID86651492

未命名化合物

收率 50%

PROCEDURE

实验过程

17,17-Bis(ethylendioxy)androstane-6β-yl nitrate was prepared in 50% yield from 3,3:17,17-bis(ethylendioxy)androstan-6β-ol following the procedure described above for the preparation of 3,3:17,17-bis(ethylendioxy)androstane-6α-yl nitrate (Prepn. 1). 1H-NMR (300 MHz, acetone-d6, ppm from TMS): δ 5.16 (m, 1H), 3.93-3.76 (m, 8H), 2.20-0.77 (m, 20H), 1.00 (s, 3H), 0.85 (s, 3H).