Dimethylformamide → HCID 86101382, compound

Participants

Reaction Conditions

Reaction Steps

A mixed solution of 4.0 g of 1-bromo-6-(4-chlorophenyl)pyrene, 2.0 g of 4-t-butylphenylboronic acid, 4.8 g of tripotassium phosphate, 0.72 g of tetrabutylammonium bromide, 52 mg of palladium acetate and 100 ml of dimethylformamide was heated and stirred under a nitrogen gas stream at 130° C. for 3 hours. The solution was cooled to room temperature and 100 ml of water was poured into the solution, followed by filtration. The resulting solid was dissolved at 140° C. by adding 100 ml of xylene. The solution was cooled to 100° C. and then filtered through Celite. The filtrate was evaporated, and then the resulting solid was washed with 50 ml of methanol and vacuum-dried to obtain 3.0 g of 1-(4-t-butylphenyl)-6-(4-chlorophenyl)pyrene.

Provenance & Evidence