Triacetoxyperiodinane → HCID 49820157, compound

Participants

Reaction Steps

To a solution of compound 3 (100 mg, 0.42 mmol) in DMSO (1 mL) was added Dess-Martin periodinane (356 mg, 0.84 mmol) at 0° C. The resulting mixture was stirred at room temperature for 20 min and poured into ice water (2 mL). The resulting precipitate was filtered, washed with water, and dried under high vacuum to furnish compound SKC-BF-01 (50 mg, 50%) as a red solid. TLC Rf=0.6 (CHCl3-MeOH, 9:1). NMR (CDCl3) δ 7.88-7.85 (m, 3H), 7.61 (d, J=6.33 Hz, 1H), 7.49 (d, J=7.6 Hz, 2H), 7.41 (d, J=10.3 Hz, 1H), 6.34 (d, J=10.3 Hz, 1H); MS (ES) m/z 253 (M+H)+.

Provenance & Evidence